Acs catalysis

Enzyme Electrochemistry for Industrial Energy Applications—A Perspective on Future Areas of Focus. John C. Ruth *. and. Alfred M. Spormann. ACS Catalysis 2021, 11, 10, 5951-5967 (Perspective) Publication Date April 30, 2021. Abstract. Full text. PDF.Seawater electrolysis is an attractive approach for producing clean hydrogen fuel in scenarios where freshwater is scarce and renewable electricity is abundant. However, chloride ions (Cl–) in seawater can accelerate electrode corrosion and participate in the undesirable chlorine evolution reaction (CER). This problem is especially acute in acidic …Oct 20, 2023 · Abstract. Herein, we present a biomimetic method for the catalytic deammoniation of diverse primary amines, including amino acids, natural products, and pharmaceuticals. This innovative approach, characterized by its operational simplicity and high selectivity, provides a rapid and easily accessible pathway to a wide range of olefin products ... Seawater electrolysis is an attractive approach for producing clean hydrogen fuel in scenarios where freshwater is scarce and renewable electricity is abundant. However, chloride ions (Cl–) in seawater can accelerate electrode corrosion and participate in the undesirable chlorine evolution reaction (CER). This problem is especially acute in acidic …It results in impressive bifunctional catalytic activities for both HER and OER and consequently enables a highly efficient water electrolyzer with a current ...Hydrogen peroxide is a valuable chemical oxidant with a wide range of applications in a variety of industrial processes, especially in water sanitization. Electrochemical synthesis of hydrogen peroxide (H2O2) through a two-electron oxygen reduction reaction (2e-ORR) or a two-electron water oxidation reaction (2e-WOR) has emerged as an appealing process …Here, we proposed a computation-driven strategy to optimize structures of enzymes via simulation-based iterative saturation mutagenesis (ISM), aiming to stabilize the spatial effects of the TS with a TSA as a placeholder. This approach was applied to redesign structures of chitinase in order to increase its catalytic activity. After three ...ACS Catalysis (2015), 5 (2), 1283-1302 CODEN: ACCACS; ISSN: 2155-5435. (American Chemical Society) A review. The chem. of nickel N-heterocyclic carbene complexes is a research area that has blossomed over the last 10 years, and a large no. of new complexes with a variety of architectural motifs are now known.Glycosyltransferases (GTs) catalyze the formation of glycosidic bonds in carbohydrates and glycoconjugates, with various outcomes depending not only on the acceptor molecules they bind but also on the type of glycosidic bond they form (C–O, C–N, C–S, or C–C). Here we show that the glucosyltransferase UGT1 from the indigo plant …ACS Catal. Website Demos & Tutorials. For Librarians & Account Managers. , and. , , and. 2024-02-11T07:44:30.911-08:00. Read the latest ASAP articles from the ACS Catalysis on ACS Publications, a trusted source for peer-reviewed journals. Check out the latest edition of the ACS Catalysis on ACS Publications, a trusted source for peer-reviewed journals. When Pt10 clusters on an iron oxide surface are heated, they first become covered in lattice oxygen and are subsequently encapsulated by an iron oxide conglomerate. Surprisingly, even the encapsulated clusters are mobile and thus undergo sintering into small, immobile nanoparticles. The authors would like to acknowledge the …The direct introduction of sp3 carbon fragments at the β position of α,β-unsaturated aldehydes is greatly complicated by competing 1,2-addition manifolds. Previous catalytic enantioselective conjugate addition methods, based on the use of organometallic reagents or ground-state iminium ion activation, could not provide general and efficient solutions. …Cathleen Crudden’s research group focuses on catalysis, chirality and materials chemistry. In particular, they are interested in developing new reactions to prepare compounds of interest to the pharmaceutical industry, specifically reactions that are enantioselective or enantiospecific. Don't fear your next interview—conquer it. This post originally appeared at LinkedIn. Follow the author here. Most people’s biggest job-hunting fear is being put on the spot by odd...If you're visiting Palma, Mallorca, you'll want to check out this AC Hotel property for its prime location, good service, and great value. We may be compensated when you click on p...If you're visiting Palma, Mallorca, you'll want to check out this AC Hotel property for its prime location, good service, and great value. We may be compensated when you click on p...Ni is the one of most efficient active sites for triggering urea electrooxidation (UOR); however, ’it is hard to achieve higher activity and stability with only the Ni site. To address issues such as dehydrogenation, C–N bond breakage, and catalyst poisoning caused by carbonaceous fragments simultaneously, manipulating a pathway via building …Here, we proposed a computation-driven strategy to optimize structures of enzymes via simulation-based iterative saturation mutagenesis (ISM), aiming to stabilize the spatial effects of the TS with a TSA as a placeholder. This approach was applied to redesign structures of chitinase in order to increase its catalytic activity. After three ...In this work, Fe–Zn catalysts were prepared, characterized, and examined for the synthesis of linear high carbon α-olefins (LAOs; C ≥ 4) directly from CO2 hydrogenation. The relationship of performance and structure has been established to unravel the role of ZnO in bimetallic Fe5C2–ZnO catalysts. A Fe2Zn1 catalyst showed high selectivity to …Ketones are among the most useful functional groups in organic synthesis. Here, we report a carbonylative cross-electrophile coupling reaction that utilizes carbon monoxide gas as both carbonyl source and reductant. The use of Pd/Rh cooperative catalysis enables the carbonylative coupling of easily accessible aryl triflates and aryl …Covalent Attachment of Cobalt Bis (Benzylaminedithiolate) to Reduced Graphene Oxide as a Thin-Film Electrocatalyst for Hydrogen Production with Remarkable Dioxygen Tolerance. Virginia A. Larson. and. Nicolai …A better fundamental understanding of the plasma-catalyst interaction and the reaction mechanism is vital for optimizing the design of catalysts for ammonia synthesis by plasma-catalysis. In this work, we report on a hybrid plasma-enhanced catalytic process for the synthesis of ammonia directly from N2 and H2 over transition metal catalysts (M/Al2O3, …ConspectusThe hydrogenative conversion of both CO and CO2 into high-value multicarbon (C2+) compounds, such as olefins, aromatic hydrocarbons, ethanol, …Biomolecular self-assembly, typically with de novo designed peptide or DNA as the building blocks, provides an effective avenue to orient and confine reactive groups into a catalytically active configuration to mimic and even rival the catalytic performance of native enzymes. In this Review, we discuss the chemical and structural properties of ...Nature Catalysis - Multiple ... van der Hoeven, J. E. S. et al. Entropic control of HD exchange rates over dilute Pd-in-Au alloy nanoparticle catalysts. ACS Catal. 11, …The rational design of high-performance electrocatalysts requires a detailed understanding of dynamic changes in catalyst properties, including oxidation states, surface area, and morphology under realistic working conditions. Oxide-derived Cu catalysts exhibit a remarkable selectivity toward multicarbon products for the electrochemical CO …January 5, 2024 Vol. 14 Issue 1. pp. 1-593. Check out a complete list of issues for the ACS Catalysis on ACS Publications, a trusted source for peer-reviewed journals.Dry reforming of methane (DRM) can convert greenhouse gases (CO2 and CH4) into value-added syngas (CO and H2), which is one of the promising approaches to achieve carbon neutrality. Designing coking resistant catalysts is still a challenge for an efficient DRM reaction. Here, we developed an efficient binary Mo–Ni catalyst through elucidating the promotional role of Mo in boosting the coking ... Anionic ligands containing a nonbonded lone pair (i.e., amido, thiolate) are well-known to cooperate with a metal center in bifunctional catalytic reactions. An NHC CoII(κ3-SNS) imine–dithiolate complex (Co-3) effects the selective hydroboration of aldehydes (vs ketones) in 4–30 min at a 1 mol % loading in benzene (NHC = 2,5 …Dec 12, 2016 · The combination of sequential biocatalytic reactions, via non-natural synthetic cascades, is a rapidly developing field and leads to the generation of complex valuable chemicals from simple precursors. As the toolbox of available biocatalysts continues to expand, so do the options for biocatalytic retrosynthesis of a target molecule, leading to alternative routes employing enzymatic ... Fischer-Tropsch synthesis (FTS) provides a nonpetroleum route for the production of value-added α-olefins from syngas. However, regulating the product distribution to promote the formation of long-chain α-olefins while maintaining low selectivity to C1 byproducts (CO2 and CH4) remains a great challenge. Herein, a series of alkali …Jan 15, 2019 · Metal organic frameworks (MOFs) have drawn wide attention as potential catalysts, offering high densities of catalytic sites in high-area porous solids, some with stabilities at high temperatures. The field is at an early stage, characterized by numerous discoveries and novel demonstrations of catalytic properties associated with the crystalline structures of MOFs, but applications of MOFs as ... Ni is the one of most efficient active sites for triggering urea electrooxidation (UOR); however, ’it is hard to achieve higher activity and stability with only the Ni site. To address issues such as dehydrogenation, C–N bond breakage, and catalyst poisoning caused by carbonaceous fragments simultaneously, manipulating a pathway via building …Acidic oxygen evolution reaction (OER) catalysts face the fundamental challenge of the trade-off between activity and durability that has not yet been well addressed. Herein, we integrate high activity of nanoparticles and good stability of bulk materials into a “macro-nano” catalyst through two-dimensional self-assembling of …Dec 4, 2020 · Biomolecular self-assembly, typically with de novo designed peptide or DNA as the building blocks, provides an effective avenue to orient and confine reactive groups into a catalytically active configuration to mimic and even rival the catalytic performance of native enzymes. In this Review, we discuss the chemical and structural properties of ... The AC Hotel Alicante, just outside the city center, checks all the boxes for modern decor, comfort, and service at an affordable price. We may be compensated when you click on pro...When you’re in the market for an air conditioning unit (AC) you should be aware that all HVAC brands are not equal in quality and reliability. This guide highlights four AC brands ...The rational design of high-performance electrocatalysts requires a detailed understanding of dynamic changes in catalyst properties, including oxidation states, surface area, and morphology under realistic working conditions. Oxide-derived Cu catalysts exhibit a remarkable selectivity toward multicarbon products for the electrochemical CO …An efficient method for the construction of 12-membered heterocycles with a trifluoromethyl group (3) was achieved via a nondecarboxylative Pd-catalyzed [6 + 6] annulation of six-membered trifluoromethyl benzo[d][1,3]oxazinones (1) with four-membered vinyl oxetanes (2). A variety of relatively large heterocycles 3 featuring a stereogenic …... ACS Catalysis and featured on the cover. Posted with permission from ACS Catalysis, July 2, 2015, 5(7). Copyright 2015 American Chemical Society. zoom ...Going beyond conventional configurations, a revolutionizing design is presented for double-atom catalysts with metal dimers vertically anchored in defective graphene forming an inverse sandwich structure. Density functional theory and machine learning are applied to unlock their potential for electrocatalyzing CO2 reduction, aiming to mitigate atmospheric CO2 levels and produce value-added ... Understanding how multicopper oxidases (MCOs) reduce oxygen in the trinuclear copper cluster (TNC) is of great importance for development of catalysts for the oxygen reduction reaction (ORR). Herein, we report a mechanistic investigation into the ORR activity of the dinuclear copper complex [Cu2L(μ-OH)]3+ (L = 2,7-bis[bis(2-pyridylmethyl)aminomethyl] …Are you looking to become a paraprofessional? The paraprofessional test is an important part of the process. It is designed to assess your knowledge and skills in order to determin...Metal-catalyzed cross-coupling reactions are extensively employed in both academia and industry for the synthesis of biaryl derivatives for applications to both medicine and material science. Application of these methods to prepare tetra-ortho-substituted biaryls leads to chiral atropisomeric products that introduce the opportunity to use catalyst control to …Dec 2, 2022 · Artwork by chemistry graduate student, Alison Sy-min Chang, featured in ACS' DEIR Cover Art series. A group of STEM individuals with varying identities are working in tandem with one another to harvest the energy from the sun to develop a collective catalytic system that addresses the initial disassembly of the systemic blockades in STEM. In her editorial, she reflects on the influence that ... ACS Catalysis 2024, Article ASAP. Di Chao, Tong-Xin Liu, Pengling Zhang, Shilu Xia, Panting Yang, Mengjiao Huang, Qingfeng Liu, Guisheng Zhang. Interrupted N-Heterocyclic Carbene-Catalyzed Radical Coupling Strategy: A Versatile Platform for Alkylation and Arylation of [60]Fullerene.Further oxidation of the complex forms {Ru V (O) (t5a-κ-N 2 O) (py) 2 } ( 2V (O) (κ-N 2 O)), which is a very efficient water oxidation catalyst, reaching a TOF MAX value of 9400 s –1 at pH 7.0, as measured via foot of the wave analysis. The key to fast kinetics for the catalytic oxidation of water to dioxygen by 2V (O) (κ-N 2 O) is due not ...The most promising approach to mitigating the greenhouse effect and tackling the energy crisis is to convert carbon dioxide into valuable liquid fuels through artificial photosynthesis. Nevertheless, most photocatalysts have poor product selectivity, low catalytic performance, and poor cycling stability. Herein, we synthesized novel UiO …The recent explosive growth in research on catalysis by supported single metal atoms proves the scientific interest in this new frontier of heterogeneous catalysis. A supported single-atom catalyst (SAC) contains only isolated individual atoms dispersed on, and/or coordinated with, the surface atoms of an appropriate support. SACs not only …Rhenium-Catalyzed Dehydration and Deoxydehydration of Alcohols and Polyols: Opportunities for the Formation of Olefins from Biomass. Suresh Raju. , Marc-Etienne …Hydrogen is important because it is involved in the process of enzyme catalysis and because it stabilizes things like nucleic acids and proteins. Hydrogen bonds with many different...Catalysis – selective catalytic reagents are superior to stoichiometric ones; they can minimize or eliminate waste, depending on the reaction, which is necessary to achieve greener chemistry Maximize Resource Efficiency – catalysis can offer more direct synthetic routes, optimizing the time, energy and materials required to make a desired ... For those looking to become a bus driver, passing the class exams is an important part of the process. Bus driver class exams cover a variety of topics, from driving laws and regul...The rational design of high-performance electrocatalysts requires a detailed understanding of dynamic changes in catalyst properties, including oxidation states, surface area, and morphology under realistic working conditions. Oxide-derived Cu catalysts exhibit a remarkable selectivity toward multicarbon products for the electrochemical CO …When you purchase a Goodman air conditioner, you want to make sure that you are covered in the event of an issue. One way to do this is by registering your Goodman AC warranty. Thi...When you’re in the market for an air conditioning unit (AC) you should be aware that all HVAC brands are not equal in quality and reliability. This guide highlights four AC brands ...Bimetallic Au–Pd alloy nanoparticles (NPs) dispersed on nanohybrid three-dimensionally ordered macroporous (3DOM) La0.6Sr0.4MnO3 (LSMO) perovskite catalysts were fabricated via the l-lysine-mediated colloidal crystal-templating and reduction routes. The obtained AuPd/3DOM LSMO samples possess a nanovoid-like 3DOM construction with …ACS Catalysis is dedicated to publishing original research on heterogeneous catalysis, homogeneous catalysis, and bio-catalysis. Application coverage includes life sciences, drug discovery ... Are you preparing for a job interview or an assessment that requires basic Microsoft Office skills? Look no further – we’ve got you covered. In this article, we will provide you wi...Published by American Chemical Society. Enzymatic degradation of polyethylene terephthlate (PET) by polyester hydrolases is currently subject to intensive research, as it is considered as a potential eco-friendly recycling method for plastic waste. However, the substrate-binding mode and the molecular mechanism of enzymatic PET hydrolysis are ...Feb 4, 2022 · ACS Catalysis (2016), 6 (4), 2382-2392 CODEN: ACCACS; ISSN: 2155-5435. ( American Chemical Society ) The electrochem. conversion of carbon dioxide (CO2) into valuable compds. is a promising route toward the valorization of this mol. of high environmental impact. CO2 hydrogenation over Fe-based catalysts is a promising pathway to mitigate emissions of this greenhouse gas and provides a possibility for crude-oil-free production of chemicals and fuels. Understanding of (i) the role of crystalline phases or/and surface species in the working catalysts, (ii) the factors affecting their formation under …A Virtual Issue focused on “Blurring the Lines Between Catalysis Subdisciplines.” ACS Catalysis continues to strive for topical breadth across …This article describes the discovery and development of a palladium-catalyzed asymmetric C–H olefination of 2-hydroxybiaryls. The strategy allows a direct assembly of optically active, axially chiral 2-substituted-2′-hydroxybiaryls from readily available precursors and demonstrates that the native hydroxy unit of the substrates can work as an efficient directing group for the C–H ... Catalysis – selective catalytic reagents are superior to stoichiometric ones; they can minimize or eliminate waste, depending on the reaction, which is necessary to achieve greener chemistry Maximize Resource Efficiency – catalysis can offer more direct synthetic routes, optimizing the time, energy and materials required to make a desired ... 3′-Phosphoadenosine-5′-phosphosulfate (PAPS) is a universal sulfate group donor for all biological sulfation reactions in living organisms. Ambitions to biomanufacture sulfate-containing compounds such as heparin and chondroitin sulfate also promote the study on PAPS in vitro synthesis. However, the established enzymatic synthesis of …Jan 24, 2022 · A series of hydrogen-atom transfer (HAT) catalysts based on the readily available and tunable 1,4-diazabicyclo[2.2.2]octane (DABCO) structure was designed, and their photoinduced HAT catalysis ability was demonstrated. The combination of our HAT catalyst with an acridinium-based organophotoredox catalyst enables efficient and site-selective C–H alkylation of substrates ranging from ... Ohio Electric Motors indicates that the main difference between AC and DC motors is the power source. AC motors are powered by an alternating current while DC motors use a direct c...A mild, efficient, and regiospecific catalytic cyclotrimerization of alkynes to form 1,2,4-substituted arenes has been discovered. From a cheap and air-stable [ ...Launched in 2010, we've hosted programming at hundreds of institutions around the world, bringing the world’s leaders in chemistry, publishing, research, science communication …Here, we have developed a new strategy for the direct C3 methylation of indoles and oxindoles ( Scheme 1 c). The process utilizes a B (C 6 F 5) 3 -mediated α-N C (sp 3 )–H bond cleavage events to activate readily available amine-based alkylating agents. Using this borane-catalyzed method, common undesired reactions, such as the N ...Mar 25, 2022 · ACS Catalysis (2017), 7 (5), 3540-3547 CODEN: ACCACS; ISSN: 2155-5435. ( American Chemical Society ) Developing highly efficient and affordable noble-metal-free catalysts toward the hydrogen evolution reaction (HER) is an important step toward the economical prodn. of hydrogen. While Fe–N–C materials exhibit great potential for catalyzing the oxygen reduction reaction (ORR), their activity origin, especially the significant activity difference in acidic and alkaline media, remains a long-standing conundrum hindering the development of such catalysts. Here, we show an unanticipated pH-dependent regulation mechanism ...A nickel-catalyzed cross-coupling to construct the C(sp2)–C(sp3) bond was developed from two sustainable biomass-based feedstocks: phenol derivatives with umpolung aldehydes. This strategy features the in situ generation of moisture/air-stable hydrazones from naturally abundant aldehydes, which act as alkyl nucleophiles under …When you’re in the market for an air conditioning unit (AC) you should be aware that all HVAC brands are not equal in quality and reliability. This guide highlights four AC brands ...For Librarians & Account Managers. ACS & Open Access. Matthew J. McKay. [email protected] Having access to mild and operationally simple techniques for attaining carbohydrate targets will be necessary to facilitate advancement in biological, medicinal, and pharmacological research. Even with the abundance of elegant reports for generating ...Perspectives in ACS Catalysis bring you a critical assessment of developing and established fields of research. Reviews in ACS Catalysis are comprehensive, …Are you a frequent shopper at Ace Hardware? If so, then you definitely want to take advantage of the My Ace Rewards program. This loyalty program is designed to reward customers li...11 Aug 2017 ... The American Chemical Society and ACS Catalysis are proud to honor Paul Chirik the Edwards S. Sanford Professor of Chemistry at Princeton ...Call for Papers: Sustainable Catalysis. Martin Sugden. Jan 12, 2024. 2 min read. Read the latest stories around cutting-edge chemistry published in ACS …The enantioselective reduction of enamides is an efficient and atom-economical way to construct chiral amine motifs. In contrast to transition-metal complex based asymmetric hydrogenation, an alternative biocatalytic way is more sustainable but remains unexploited. The challenge lies in the redox potential mismatch between the …ACS Catalysis (2021), 11 (3), 1242-1247 CODEN: ACCACS; ISSN: 2155-5435. ( American Chemical Society ) The manipulation of photoelectrodes' electron-hole pairs toward low recombination is the fundamental strategy to achieve high solar-to-hydrogen conversion efficiency in photoelectrochem. This week we’re improving our public speaking skills with the help of expert Carmine Gallo, author of Talk Like TED: The 9 Public-Speaking Secrets of the World’s Top Minds, who tel...Hydrogen bond-based organocatalysts rely on networks of attractive noncovalent interactions (NCIs) to impart enantioselectivity. As a specific example, aryl pyrrolidine substituted urea, thiourea, and …ACS Catalysis 2022, 12, 18, 11002-11014 (Research Article) ACS Editors' Choice® is a collection designed to feature scientific articles of broad public interest. Read the latest articlesAug 5, 2022 · Metal–organic frameworks (MOFs) and coordination polymers (CPs) are potential candidates for high-performance photocatalysts because of their high tunability of electronic and structural properties. For example, MOFs and CPs having a high specific surface area (∼1000 m2 g–1) have been applied as visible-light-driven photocatalysts for CO2 reduction and water splitting. Herein, we show a ... Jan 29, 2021 · Synergistic effects have been discussed extensively in bimetallic heterogeneous catalysis, but it remains unclear how the effects function at the atomic scale. Here, we report a dual single-atom catalyst (DSAC) Ir1Mo1/TiO2 displaying much greater catalytic chemoselectivity (>96%, at 100% conversion) than comparable single-atom catalysts (SACs) Ir1/TiO2 (38%, at 87% conversion) and Mo1/TiO2 (no ... ACS on Campus. The American Chemical Society’s premier outreach program. Launched in 2010, we've hosted programming at hundreds of institutions around the world, bringing the world’s leaders in chemistry, publishing, research, science communication and career development right to your doorstep.That reaction requires two steps with a palladium catalyst (J. Org. Chem. 2021, DOI: 10.1021/acs.joc.1c01073). Chirik’s group has also published studies in …Ni is the one of most efficient active sites for triggering urea electrooxidation (UOR); however, ’it is hard to achieve higher activity and stability with only the Ni site. To address issues such as dehydrogenation, C–N bond breakage, and catalyst poisoning caused by carbonaceous fragments simultaneously, manipulating a pathway via building …The design of electrocatalysts capable of selectively reducing nitrate to ammonia is gaining interest as a means of transforming waste into fertilizers. However, most prior investigations of prototypical electrocatalysts, such as polycrystalline Pd and Pt, have focused on unraveling the mechanisms responsible for the selective reduction of nitrate to nitrogen …When it comes to cooling your home, there are several options available in the market. Two of the most popular types of air conditioners are portable ACs and window ACs. In this ar...Chiral oxazolidinones are a class of important heterocyclic compounds in pharmaceutical chemistry due to their biological activity. Halohydrin dehalogenase-catalyzed epoxide ring-opening reaction with cyanate offers an attractive approach to the synthesis of chiral oxazolidinones, but the α/β-regioselectivity and stereoselectivity are …Rhenium-Catalyzed Dehydration and Deoxydehydration of Alcohols and Polyols: Opportunities for the Formation of Olefins from Biomass. Suresh Raju. , Marc-Etienne …Nature has provided a fantastic array of enzymes that are responsible for essential biochemical functions but not usually suitable for technological applications. Not content with the natural repertoire, protein engineering holds promise to extend the applications of improved enzymes with tailored properties. However, engineering of robust proteins …Mar 25, 2020 · We herein report the fabrication of a bifunctional iron nanocomposite catalyst, in which two catalytically active sites of Fe–Nx and Fe phosphate, as oxidation and Lewis acid sites, were simultaneously integrated into a hierarchical N,P-dual doped porous carbon. As a bifunctional catalyst, it exhibited high efficiency for direct oxidative cleavage of alkenes into ketones or their oxidation ... Oct 20, 2023 · Abstract. Herein, we present a biomimetic method for the catalytic deammoniation of diverse primary amines, including amino acids, natural products, and pharmaceuticals. This innovative approach, characterized by its operational simplicity and high selectivity, provides a rapid and easily accessible pathway to a wide range of olefin products ... When you purchase a Goodman air conditioner, you want to make sure that you are covered in the event of an issue. One way to do this is by registering your Goodman AC warranty. Thi...Hydrogen is important because it is involved in the process of enzyme catalysis and because it stabilizes things like nucleic acids and proteins. Hydrogen bonds with many different...Most people use the term AC condenser to refer to the part of the air conditioning system that sits outside the home, even though this part of the system has more components that j...A variety of atomically dispersed transition-metal-anchored nitrogen-doped carbon (M–N–C) electrocatalysts have shown encouraging electrochemical CO2 reduction reaction (CO2RR) performance, with the underlying fundamentals of central transition-metal atom determined CO2RR activity and selectivity yet remaining unclear. Herein, a …The enantioselective reduction of enamides is an efficient and atom-economical way to construct chiral amine motifs. In contrast to transition-metal complex based asymmetric hydrogenation, an alternative biocatalytic way is more sustainable but remains unexploited. The challenge lies in the redox potential mismatch between the …For those looking to become a bus driver, passing the class exams is an important part of the process. Bus driver class exams cover a variety of topics, from driving laws and regul...In this work, we develop a synthetic route to synthesize and integrate thin mesoporous silica nanowires into three-dimensional (3D) networks. Hierarchical pore ...Copper-Catalyzed Synthesis of Masked (Hetero)Aryl Sulfinates. Stereoselective Synthesis of Either. 1155 Sixteenth Street N.W. About ACS Publications. ACS & Open Access. ACS Publications Blog. Journals A-Z. ACS Publishing Center. 2024-02-15T07:54:50.884-08:00.Enzyme Electrochemistry for Industrial Energy Applications—A Perspective on Future Areas of Focus. John C. Ruth *. and. Alfred M. Spormann. ACS Catalysis 2021, 11, 10, 5951-5967 (Perspective) Publication Date April 30, 2021. Abstract. Full text. PDF.Cu-oxide catalysts have a tendency to deactivate dramatically in reverse water gas shift (RWGS) reaction, because of the aggregation of supported copper particles at high temperatures. Herein, β-Mo2C, which is a typical type of transition-metal carbide, has been demonstrated to be capable of dispersing and stabilizing copper particles. Cu/β-Mo2C …Heterogeneous catalysis is one of the pillars of chemical and energy industries. As research on this important topic advances, heterogeneous catalysis will be a central science in driving the transition to their eventual carbon neutral operation due to the ease of separation and reusability. ... ACS and Elsevier journals. Prof. Luque was named ... | Cmtzjqvw (article) | Mykjyxc.